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I always want that ONE shot, she'll walk up with her little P&S and snap one, then it's "I'm done, ready to go?"

Help her find something else to do. For example, my ex used to be a botanist (before she became a doctor). When I spend a long time composing a nature picture, she is perfectly content to pull out the plant dissection kit, the 900 power microscope, the Jepson Manual, and her notebook, and entertain herself with some field biology.